The Radical Cation +: Novel Source of Iron(II) Carbonyl Complexes

DOI: 10.1039/c39800000775

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 775 (1980)

Update date:2022-08-02

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Authors:

Baker, Paul K.

Broadley, Karen

Connelly, Neil G.

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Article abstract of DOI:10.1039/c39800000775

The iron(I) complex + undergoes novel radical-radical coupling and redox reactions, with paramagnetic (NO, NO2, etc.) and diamagnetic (^-, S2C^-P⁺R3, etc.) ligands, respectively, to give iron(II) carb

Full text of DOI:10.1039/c39800000775

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Product name:[Fe(CO)2(P(C₆H₅)3)2((CH₃)2NCS₂)]⁽¹⁺⁾*PF₆^(1-)=[Fe(CO)2(P(C₆H₅)3)2((CH₃)2NCS₂)][PF₆]

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