Vicarious nucleophilic substitution of hydrogen proceeding via heterocyclic ring opening

DOI: 10.1016/0040-4020(95)01104-8

Source and publish data:

Tetrahedron p. 3189 - 3194 (1996)

Update date:2022-08-05

Topics:

Authors:

Makosza, Mieczyslaw

Sypniewski, Michal

Glinka, Tomasz

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Article abstract of DOI:10.1016/0040-4020(95)01104-8

Carbanions of five-membered S-heterocycles react with nitroarenes via the ring-opening VNS reaction or oxidative nucleophilic substitution of hydrogen. The reaction course is affected by rigidity of the ring.

Full text of DOI:10.1016/0040-4020(95)01104-8

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