Vicarious nucleophilic substitution of hydrogen proceeding via heterocyclic ring opening

DOI: 10.1016/0040-4020(95)01104-8

Source and publish data:

Tetrahedron p. 3189 - 3194 (1996)

Update date:2022-08-05

Topics:

Authors:

Makosza, Mieczyslaw

Sypniewski, Michal

Glinka, Tomasz

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4020(95)01104-8

Carbanions of five-membered S-heterocycles react with nitroarenes via the ring-opening VNS reaction or oxidative nucleophilic substitution of hydrogen. The reaction course is affected by rigidity of the ring.

Full text of DOI:10.1016/0040-4020(95)01104-8

Products guided by the article

Product name:N,N-dimethyl-2-(2-nitro-phenyl)-acetamide

Cas No:76016-34-7

R&D Labs maybe for 76016-34-7

Suzhou CarbonWell Pharma-Tech Co., Ltd

Contact:Tel: + 86 (0)512-8898-1216; + 86-18606258602

Address:2358 Changan Road, Wujiang Scientific Innovation Park, Wujiang, Jiangsu Province, P. R. China 215200
Shanghai KFSL Pharmaceutical Technology Co.,Ltd.

Contact:+86-21-39971718

Address:859 jiadingchengliu shanghai
WANGWEIPING(expird)

Contact:0086 16537861366

Address:building 17, shibei district Qingdao, shandong china
ShangHai Ruiyi Medical Technology Co.,Ltd.

Contact:+86-21-54718086

Address:No951 Jianchuan RD，Minhang District
Hangzhou utanpharma Co., Ltd

Contact:86-571-87758773

Address:Room604 ,6F, Block A1-3 Xixi Plaza,No. 588 Wenyi West RD, Hangzhou,310012, China

Relevant to this article

The uncatalyzed ring opening of hetaryloxides with nitrogen nucleophiles. A dichotomy of regioselectivity

Doi:10.1016/S0040-4039(00)60203-4
(1992)
Protecting groups transfer: Unusual method of removal of tr and TBDMS groups by transetherification

Doi:10.1080/15257770802257846
(2008)
Doi:10.1039/jr9630002385
(1963)
Crystal structure and nuclear magnetic resonance and infrared spectra of 9,9-dideuteriothioxanthenium bis(carboethoxy)methylide, dimethyl 9-(1,4-dimethylthioxanthenyl)malonate, thioxanthonium bis(carbomethoxy)methylide, and related compounds

Doi:10.1021/jo00322a008
(1981)
Stereoselective Synthesis of Alcohols. 8. Diastereoselective Synthesis of β-Methylhomoallyl Alcohols via Crotylboronates

Doi:10.1021/jo00320a015
(1981)
SAR studies of piperidine-based analogues of cocaine. Part 3: Oxadiazoles

Doi:10.1016/S0960-894X(01)00379-1
(2001)

Article Doi