Vicarious nucleophilic substitution of hydrogen proceeding via heterocyclic ring opening

DOI: 10.1016/0040-4020(95)01104-8

Source and publish data:

Tetrahedron p. 3189 - 3194 (1996)

Update date:2022-08-05

Topics:

Authors:

Makosza, Mieczyslaw

Sypniewski, Michal

Glinka, Tomasz

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4020(95)01104-8

Carbanions of five-membered S-heterocycles react with nitroarenes via the ring-opening VNS reaction or oxidative nucleophilic substitution of hydrogen. The reaction course is affected by rigidity of the ring.

Full text of DOI:10.1016/0040-4020(95)01104-8

Products guided by the article

Product name:N,N-dimethyl-2-(2-nitro-phenyl)-acetamide

Cas No:76016-34-7

R&D Labs maybe for 76016-34-7

JIANGSU GRAND XINYI PHARMACEUTICAL CO.,LTD

website:http://www.xypharm.com/

Contact:+86-515-84383317

Address:Chenli Road,Costal Chemical Area Binhai,Yancheng, Jiangsu,China
ChangZhou XiaQing Chemical Co., Ltd.

Contact:+86-519-88721665

Address:3# Hengluo Road, Henglin Town, Changzhou City, Jiangsu Province，China
Sichuan Jisheng BioPharmaceutical Co., Ltd.

website:http://www.jisheng-peptide.com/

Contact:86-833-2598983

Address:No. 3, Jianye Road, High-tech Zone, Leshan City, Sichuan, China
Nantong Chem-land Co., Ltd.

Contact:86 513 85512619

Address:Rm.1306, Building A, Wenfeng Mansion,168 Gongnong Road, Nantong Jiangsu China
Yicheng Goto Pharmaceuticals Co.,Ltd.

Contact:+86 710 3423122

Address:5th Floor,East Gate of Building #2,Servo-Industrial Park,1st Qilin Road,Xiangyang,Hubei,China

Relevant to this article

The uncatalyzed ring opening of hetaryloxides with nitrogen nucleophiles. A dichotomy of regioselectivity

Doi:10.1016/S0040-4039(00)60203-4
(1992)
Protecting groups transfer: Unusual method of removal of tr and TBDMS groups by transetherification

Doi:10.1080/15257770802257846
(2008)
Doi:10.1039/jr9630002385
(1963)
Crystal structure and nuclear magnetic resonance and infrared spectra of 9,9-dideuteriothioxanthenium bis(carboethoxy)methylide, dimethyl 9-(1,4-dimethylthioxanthenyl)malonate, thioxanthonium bis(carbomethoxy)methylide, and related compounds

Doi:10.1021/jo00322a008
(1981)
Stereoselective Synthesis of Alcohols. 8. Diastereoselective Synthesis of β-Methylhomoallyl Alcohols via Crotylboronates

Doi:10.1021/jo00320a015
(1981)
SAR studies of piperidine-based analogues of cocaine. Part 3: Oxadiazoles

Doi:10.1016/S0960-894X(01)00379-1
(2001)

Article Doi