Chemistry - A European Journal p. 5860 - 5863 (2012)
Update date:2022-09-26
Topics:
Cahiez, Gerard
Gager, Olivier
Buendia, Julien
Patinote, Cindy
Ironing out the kinks: Efficient new catalytic systems based on iron thiolates are described for the iron-catalyzed cross-coupling of alkyl Grignard reagents with alkenyl halides (see scheme). The reaction is highly chemo- and stereoselective. With this new procedure, the use of N-methylpyrrolidone as a co-solvent is no longer required. Copyright
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