Cis- and trans-platinum complexes of anilines. A study of isormerization reactions

DOI: 10.1016/S0020-1693(00)89152-5

Source and publish data:

Inorganica Chimica Acta p. 269 - 271 (1982)

Update date:2022-09-26

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Authors:

Kong, Pi-Chang

Rochon Rochon

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Article abstract of DOI:10.1016/S0020-1693(00)89152-5

Cis- and trans-[PtL₂Cl₂] (where L = aniline, 2,5-dimethylaniline and p-toluidine) have been synthesized. The cis-compounds can be isolated isomerically pure from the reaction of K[PtLCl₃] and L in a mixture of water and ethanol. The trans-isomers are obtained from the isomerization of the cis-compounds. The isomers can be identified from their infrared spectra. The isomer pair, [Pt(2,5-dimethyl-aniline)₂Cl₂] respond to Kurnakov's test in acetone solution at room temperature. Trans-[Pt(2,5-dimethylaniline)₂(thiourea)₂] Cl₂ has been characterized.

Full text of DOI:10.1016/S0020-1693(00)89152-5

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Product name:K⁽¹⁺⁾*Pt(C₆H₅NH₂)Cl₃^(1-)=K(Pt(C₆H₅NH₂)Cl₃)

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