Tetrahedron Letters p. 4177 - 4180 (1988)
Update date:2022-09-26
Topics:
Capozzi, Francesco
Capozzi, Giuseppe
Menichetti, Stefano
The reaction of bis(trimethylsilyl)sulphide with bromine at -78 deg C forms trimethylsilylsulphenyl bromide which reacts with alkenes to give thiiranes.Trimethylsilyl bromide and iodide catalytically desulphurize thiiranes to alkenes.
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