Synthesis p. 947 - 949 (1992)
Update date:2022-08-02
Topics: Asymmetric synthesis Enantiomer Catalyst Stereochemistry Chirality Heterocycle Chiral building block Amino group
Dehmlow
Westerheide
Methioninol [2-amino-4-(methylthio)butan-1-ol] is converted into (S)-4,5-dihydro-4-[2-(methylthio)ethyl]-2-phenyl-1,3-oxazole (1). An acid-catalyzed rearrangement of 1 gives (S)-(-)-3-(benzoylamino)tetrahydrothiophene (2) in a stereospecific fashion. The
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Doi:10.1016/S0040-4039(01)90556-8
(1981)Doi:10.1055/s-2004-829076
(2004)Doi:10.1021/jo00932a011
(1974)Doi:10.1021/ja046586x
(2004)Doi:10.1016/j.tetasy.2004.05.043
(2004)Doi:10.1021/jo00322a018
(1981)
