FORMATION OF ORGANOMETALLIC COMPLEXES OF PLATINUM(II) AND PLATINUM(IV) IN REACTIONS OF PtCl62- WITH ALKANES, OLEFINS AND AROMATICS INDUCED BY γ-IRRADIATION

DOI: 10.1016/0022-328X(84)80061-3

Source and publish data:

Journal of Organometallic Chemistry p. C12 - C14 (1984)

Update date:2022-08-03

Topics:

Authors:

Serdobov, Mikhail V.

Nizova, Galina V.

Shul'Pin, Georgiy B.

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Article abstract of DOI:10.1016/0022-328X(84)80061-3

γ-Irradiation of solutions of the ion PtCl5^2- and n-hexane (or alkene) in MeCO2H affords a ?-olefin complex of platinum(II); ?-aryl complexes of platinum(IV) are formed in analogous reactions with aromatic compounds.

Full text of DOI:10.1016/0022-328X(84)80061-3

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Product name:[CH₃OC₆H₄PtCl₄(NH₃)]^(1-)*NH₄⁽¹⁺⁾ = [CH₃OC₆H₄PtCl₄NH₃]NH₄

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