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SYNTHESIS OF 9,10-BENZOTETRACYCLO2,4.03,5>DECA-1(7),9-DIEN-6-ONE, A VALENCE ISOMER OF BENZAZULEN-9(10H)-ONE

DOI: 10.1246/cl.1980.1103

Source and publish data:

Chemistry Letters p. 1103 - 1106 (1980)

Update date:2022-08-04

Topics:

Authors:

Sugihara, YoshikazuSugihara, Yoshikazu

Sugimura, TakashiSugimura, Takashi

Murata, IchiroMurata, Ichiro

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Article abstract of DOI:10.1246/cl.1980.1103

9,10-Benzotetracyclo<5.3.0.02,4.03,5>deca-1(7),9-dien-6-one (2), a valence isomer of benzazulen-9(10H)-one (3), has been synthesized from 5,6-benzobicyclo<3.2.0>hepten-2-one utilizing the oxa-di-?-methane rearrangement.

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Full text of DOI:10.1246/cl.1980.1103

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