Journal of Physical Chemistry p. 4403 - 4407 (1986)
Update date:2022-08-05
Topics:
Hayashy, Hisaharu
Sakaguchi, Yoshio
Murai, Hisao
l'Haya Yasumasa J.
Photoreduction of benzophenone, acetophenone, and 2-acetonaphthone with tri-n-butylstannane at room temperature in some solvents was studied by CIDEP.The ketyl radicals were shown to be produced in the 2-propanol solution of benzophenone and in the benzene and n-heptane solutions of acetophenone.On the other hand, cyclohexadienyl-type radicals were found to be produced in the 2-propanol, benzene, and n-heptane solutions of acetophenone and 2-acetonaphthone.These two types of radicals, ketyl and cyclohexadienyl-types ones, were shown to be produced through the n?* and ??* characters of triplet ketones, respectively.
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