Journal of Organometallic Chemistry p. 299 - 308 (1981)
Update date:2022-08-04
Topics:
Brown, Herbert C.
Kulkarni, Surendra U.
Practical methods for the synthesis of dialkylboranes (R2BH) via the hydridation of dialkylhaloboranes (R2BX) have been developed.Convenient methods available for the preparation of R2BX via the hydroboration of alkenes with monohaloborane complexes (H2BX*SMe2) make this approach valuable for the preparation of various dialkylboranes, R2BH, many of which are not available by direct hydroboration of alkenes with borane itself.The suitability of various hydriding agents, such as borane derivatives, complex metal hydrides, and alkoxy metal hydrides, for the hydridationof R2BX was examined, utilizing B-halo-9-borabicyclo<3.3.1>nonane as a representative dialkylhaloborane.In this case, the unusual stability of the resulting dialkylborane, 9-BBN, permits direct estimation of the reaction products by 11B NMR spectroscopy.The generality of the procedure has been demonstrated.
Baicao Pharmaceutical Co., Ltd.
website:http://www.jxbaicao.com
Contact:+86-796-8113329
Address:It (country) economic and technological development zone of the jinggang mountains
Contact:0510-85393305
Address:1619 Huishan Avenue, Huishan District, Wuxi,
Contact:21-7631221 15884421033
Address:326 Science and technology,Shanghai,China
Contact:+86-21-38122007
Address:2, Lane 1123, Kangqiao Road, Pudong New Area, Shanghai
Contact:+86-025-52406782
Address:8 Taizishan Rd., Yanjiang Industrial Development Area, Nanjing, Jiangsu, China.
Doi:10.1016/j.tetlet.2012.12.124
(2013)Doi:10.1021/ma401344d
(2013)Doi:10.1080/00397911.2011.609301
(2013)Doi:10.1016/j.bmcl.2012.12.053
(2013)Doi:10.1016/j.bmcl.2013.01.004
(2013)Doi:10.1016/0957-4166(92)80023-P
(1992)
