Copper(I)-Cabon Monoxide Chemistry: Genesis and Chemical and Structural Properties of Copper(I) Terminal and Bridging Carbonyls

Article abstract of DOI:10.1021/ja00379a009

Carbonylation of copper(I) benzoate in methanol carried out in the presence of N,N,N',N'-tetramethylethylenediamine, tmen, or N,N,N',N'-tetramethylpropylenediamine, tmpn, led to the isolation of the only bridging copper(I) carbonyls so far identified,