Carbon-13 Nuclear Magnetic Resonance Studies of Carbocations. 5. Effect of Increasing Electron Demand on the Carbon-13 Chemical Shifts of 3-Aryl-3-pentyl and 2-Aryl-2-adamantyl Carbocations. Correlation of ΔδC+ with Edhanced Substituent Constan

DOI: 10.1021/jo00321a025

Source and publish data:

Journal of Organic Chemistry p. 1650 - 1653 (1981)

Update date:2022-08-02

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Authors:

Kelly, David P.

Jenkins, Margot J.

Mantello, Robert A.

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Article abstract of DOI:10.1021/jo00321a025

The ¹³C chemical shifts for a range of meta- and para-substituted 3-phenyl-3-pentyl and 2-phenyl-2-adamantyl carbocations have been measured in FSO3H/SbF5/SO2ClF solutions.The cationic carbon substituent chemical shifts (Δδ^C+) show o

Full text of DOI:10.1021/jo00321a025

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