ACID CATALYSED REARRANGEMENTS OF ARBOREOL: A BIOMIMETIC SYNTHESIS OF GMELANONE

DOI: 10.1016/S0040-4039(00)78645-X

Source and publish data:

Tetrahedron Letters p. 2919 - 2922 (1980)

Update date:2022-08-05

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Authors:

Row, Ramachandra L.

Ventkateswarlu, Reveru

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Article abstract of DOI:10.1016/S0040-4039(00)78645-X

Arboreol rearranges under acid conditions to yield gmelanone, a reaction related to the possible biosynthesis of gmelanone, and one which confirms the absolute configuration of gmelanone.Gmelanone itself is unstable to acid and on exposure undergoes a ring opening reaction to give a new class of lignan.

Full text of DOI:10.1016/S0040-4039(00)78645-X

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