Extracyclic Stereocontrol in Addition Reaction of Crotylsilanes with 2-Substituted 2-Cyclopentenones. Stereodivergent Synthesis of (+)-Neonepetalacton and (+)-Isoneonepetalactone

DOI: 10.1246/cl.1990.1999

Source and publish data:

Chemistry Letters p. 1999 - 2002 (1990)

Update date:2022-08-03

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Authors:

Pan, Li-Rui

Tokoroyama, Takashi

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Article abstract of DOI:10.1246/cl.1990.1999

The addition reaction of E- and Z-crotylsilanes with 2-substituted 2-cyclopentenones showed the preference of erythro and threo products respectively.The refinement of the selectivity was investigated and the result was utilized for efficient syntheses of

Full text of DOI:10.1246/cl.1990.1999

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