Tetrahedron Letters p. 2253 - 2256 (1980)
Update date:2022-08-04
Topics:
Penco, Sergio
Angelucci, Francesco
Ballabio, Marzia
Vigevani, Aristide
Arcamone, Federico
Stereoselective epoxidation of 1, the 7,8-unsaturated derivative of daunomycinone, followed by trans opening of the epoxide 2, afforded 8(R)-methoxydaunomycinone 6a: its configuration at C-8 was determined by chemical correlations and PMR studies.
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