Tandem Transannular Radical Cyclizations. Total Synthesis of (+/-)-Modhephene and (+/-)-Epi-Modhephene

DOI: 10.1016/S0040-4020(01)80321-5

Source and publish data:

Tetrahedron p. 755 - 770 (1993)

Update date:2022-08-02

Topics:

Authors:

Curran, Dennis P.

Shen, Wang

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4020(01)80321-5

Modhephene and epi-modhephene have been synthesized by a new tandem transannular radical cyclization strategy.The key tandem cyclization is conducted by the Barton thiohydroxamate method with an exo(methylene)cyclooctane.

Full text of DOI:10.1016/S0040-4020(01)80321-5

Products guided by the article

Product name:(±)-epimodhephene

Cas No:76739-65-6

R&D Labs maybe for 76739-65-6

NingBO Hong Xiang Biochem.Co.Ltd

website:http://www.hxbiochem.com

Contact:0574-66003444

Address:Ning Bo Bei Lun
China Synchem Technology Co.,Ltd

website:http://www.cnsynchem.com

Contact:+86-0552-4929311

Address:No.217 Daqing Road
Binzhou Holly Pharmaceutical Co.,Ltd.

Contact:74517

Address:No.15 Dapu Road,Huangpu District Shanghai,P.R.China
Beijing Apis Biotechnology Co., Ltd.

Contact:86-010-67856775-8551

Address:NO.4PUHUANGYU ROAD,FENTAI DISTRICT, BEIJING, CHINA
Lyan Limited

Contact:86-021-52418058

Address:8/F, Building 6, Guiping Road No.333, Shanghai, 200233, China

Relevant to this article

Tandem concurrent processes: One-pot single-catalyst biohydrogen transfer for the simultaneous preparation of enantiopure secondary alcohols

Doi:10.1021/jo802350f
(2009)
A Synthetic Route to Chiral Benzo-Fused N-Heterocycles via Sequential Intramolecular Hydroamination and Asymmetric Hydrogenation of Anilino-Alkynes

Doi:10.1021/acs.organomet.9b00183
(2019)
Doi:10.1021/ja01257a060
(1942)
Asymmetric synthesis of α,α-difluoro-β-amino phosphonic acids using sulfinimines

Doi:10.1016/j.tetlet.2004.06.126
(2004)
N-Amino-exo-3,6-epoxy-1,2,3,6-tetrahydrophthalimide as an active aminoaziridinating agent

Doi:10.1002/ejoc.200900326
(2009)
Reductive Deamination with Hydrosilanes Catalyzed by B(C6F5)3

Doi:10.1002/anie.202004651
(2020)

Article Doi