Tandem Transannular Radical Cyclizations. Total Synthesis of (+/-)-Modhephene and (+/-)-Epi-Modhephene

DOI: 10.1016/S0040-4020(01)80321-5

Source and publish data:

Tetrahedron p. 755 - 770 (1993)

Update date:2022-08-02

Topics:

Authors:

Curran, Dennis P.

Shen, Wang

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Article abstract of DOI:10.1016/S0040-4020(01)80321-5

Modhephene and epi-modhephene have been synthesized by a new tandem transannular radical cyclization strategy.The key tandem cyclization is conducted by the Barton thiohydroxamate method with an exo(methylene)cyclooctane.

Full text of DOI:10.1016/S0040-4020(01)80321-5

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Product name:(±)-epimodhephene

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