New Methods for Metal-Carbon Bond Formation; Reactions of (OC)5MnSiMe3 with Cyclic Ethers

DOI: 10.1039/c39800001260

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1260 - 1261 (1980)

Update date:2022-08-04

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Authors:

Brinkman, Kerry C.

Gladysz, John A.

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Article abstract of DOI:10.1039/c39800001260

When (OC)5MnSiMe3 (1) is treated with cyclic ethers (ring size <= 5), ring opening and metal-carbon bond formation occurs; under 200 lb in^-2 of CO, high yields of products (OC)5Mn(COR) can be obtained.

Full text of DOI:10.1039/c39800001260

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