New Methods for Metal-Carbon Bond Formation; Reactions of (OC)5MnSiMe3 with Cyclic Ethers

DOI: 10.1039/c39800001260

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1260 - 1261 (1980)

Update date:2022-08-04

Topics:

Authors:

Brinkman, Kerry C.

Gladysz, John A.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39800001260

When (OC)5MnSiMe3 (1) is treated with cyclic ethers (ring size <= 5), ring opening and metal-carbon bond formation occurs; under 200 lb in^-2 of CO, high yields of products (OC)5Mn(COR) can be obtained.

Full text of DOI:10.1039/c39800001260

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:trans-(CO)5MnCOCH(CH₂)4CHOSi(CH₃)3

Cas No:77036-21-6

R&D Labs maybe for 77036-21-6

Linyi Shengxin Pharmaceutical R&D Co., Ltd

Contact:+86-18653953873

Address:West First of Yufeng Road, Yishui County
MS( MAOSHENG )Chemical CO.,LTD

Contact:+86-519-82726678.82726378

Address:TAOXI INDUSTRY ZONE JINTAN
Hubei Vanz Pharm Co.,Ltd

website:http://www.vanzpharm.com/en/index.html

Contact:86-27-84492310

Address:FANHU INDUSTRY PARK
Tomo Pharma Chem Co., Limited

Contact:+86-158-05817090

Address:ROOM 9F, FLAT 2, GUODU DEVELOPING BLDG, No.182, ZHAOHUI ROAD
Reliable Pharma Technology (Shanghai) Co., Ltd.

Contact:0086-21-67676847-8008

Address:Lane 1500, No.68, Xinfei Road, Songjiang District, Shanghai, 201611, P.R.China.

Relevant to this article

Doi:10.1021/jo01279a077
(1967)
Phase-transfer Catalysis Using Chiral Catalysts. Influence of the Structure of the Catalyst on Stereoselectivity. Part 3.

Doi:10.1039/P19810000574
(1981)
Doi:10.1021/jo01200a007
(1942)
BISINDOLES. 7. SYNTHESIS OF DI(5-INDOLYL) SULFONE

Doi:10.1007/BF00504111
(1980)
Direct difunctionalization of alkenes with sulfinic acids and NBS leading to β-bromo sulfones

Doi:10.1016/j.tetlet.2015.02.043
(2015)
Thallium in Organic Synthesis. 60. 2,6-Diaryl-3,7-dioxabicyclo<3.3.0>octane-4,8-dione Lignans by Oxidative Dimerization of 4-Alkoxycinnamic Acids with Thallium(III) Trifluoroacetate or Cobalt(III) Trifluoride

Doi:10.1021/jo00328a018
(1981)

Article Doi