Tetrahedron Letters p. 4335 - 4338 (1980)
Update date:2022-08-03
Topics:
Raucher, Stanley
Macdonald, James E.
Lawrwence, Ross F.
Trimethyl β-(methoxy)ortopropionate, a compound which is thermally stable at 190 deg C for proplonged times, may be utilized as a synthon for the preparation of methyl α-substituted acrylates via Claisen ortho ester rearrangement with allylic alcohols followed by β-elimination of methanol with base.
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(2021)
