Tetrahedron Letters p. 4335 - 4338 (1980)
Update date:2022-08-03
Topics:
Raucher, Stanley
Macdonald, James E.
Lawrwence, Ross F.
Trimethyl β-(methoxy)ortopropionate, a compound which is thermally stable at 190 deg C for proplonged times, may be utilized as a synthon for the preparation of methyl α-substituted acrylates via Claisen ortho ester rearrangement with allylic alcohols followed by β-elimination of methanol with base.
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(1981)Doi:10.1021/jm00138a027
(1981)Doi:10.1002/ejoc.200400307
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(2010)Doi:10.1021/jo00326a035
(1981)Doi:10.1016/j.ejmech.2021.113326
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