Stereochemistry of Halogenation of Nitronate Adducts from 4-Methoxy-1-nitronaphthalene and RMgX to 1-Halogeno-2-alkyl-4-methoxy-1-nitro-1,2-dihydronaphthalenes and of Subsequent Elimination to Alkylhalogenonaphthalenes. Crystal Structure of a Tetrahydrona

Article abstract of DOI:10.1021/jo00328a024

Studies on the stereochemical aspects of the reactivity of nitronate adducts from RMgX and nitroarenic systems have been extended to their reaction with electrophilic reagents other than H3O⁺.The reaction of C-bromination of the 1,4-adducts fro