The Reaction of Di-iodoacetylene with : Formation of and

DOI: 10.1039/c39880000047

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 47 - 49 (1988)

Update date:2022-08-04

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Authors:

Davies, Julian A.

Pinkerton, A. Alan

Syed, Rashid

Vilmer, Mark

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Article abstract of DOI:10.1039/c39880000047

The complex reacts with di-iodoacetylene to yield and , which have been characterized by spectroscopic methods and by X-ray crystallography; formation of the bridged dichlorovinylidene complex involves a formal 1,2-halide shift accompanied by C-I/Pd-Cl bond methathesis.

Full text of DOI:10.1039/c39880000047

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