Tetrahedron Letters p. 3689 - 3692 (1985)
Update date:2022-08-02
Topics:
Paulsen, Hans
Schueller, Matthias
Nashed, Mina A.
Heitmann, Axel
Redlich, Hartmut
Chain extension of 2,3:5,6-di-O-isopropylidene-D-manno-furanose 2 with 2-lithio-1,3-dithiane gives stereoselectively a derivative of D-glycero-D-galacto-heptose 3.Conversion of the heptose 2 by reduction of the aldehydo function and oxidation of the 7-OH group yields the D-glycero-D-manno-heptose 18.
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