Chemistry Letters p. 1047 - 1050 (1987)
Update date:2022-08-04
Topics: Benzene ring Stability Methyl Group Experimental Benzyl cation Gas phase Substituent effect Interactions Chemical groups Organic Molecule
Mishima, Masaaki
Arima, Kiyoshi
Usui, Satoshi
Fujio, Mizue
Tsuno, Yuho
Chloride ion affinities of substituted benzyl cations in the gas phase have been determined by means of an ICR mass spectrometer.The substituent effect has been analyzed in terms of the LArSr Eq., giving a p=13.6 and r+=1.31.
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