A STEREOSPECIFIC SYNTHESIS OF CONJUGATED (E,Z)- AND (Z,Z)-ALKADIENES BY A PALLADIUM-CATALYZED CROSS-COUPLING REACTION OF 1-ALKENYLBORANES WITH 1-ALKENYL BROMIDES

DOI: 10.1016/0040-4039(81)80166-9

Source and publish data:

Tetrahedron Letters p. 127 - 130 (1981)

Update date:2022-08-02

Topics: Palladium-catalyzed cross-coupling Oxidative Addition Reductive Elimination Stereoselectivity Transmetalation Catalytic Cycle Stereospecific synthesis

Authors:

Miyaura, Norio

Suginome, Hiroshi

Suzuki, Akira

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Article abstract of DOI:10.1016/0040-4039(81)80166-9

The reactions of (Z)-1-alkenyldisiamylboranes with (Z)- or (E)-1-alkenyl bromides in the presence of a catalytic amount of tetrakis(triphenylphosphine)palladium and sodium ethoxide gave the corresponding conjugated (Z,Z)- or (Z,E)-alkadiene with high ster

Full text of DOI:10.1016/0040-4039(81)80166-9

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