Tetrahedron Letters p. 127 - 130 (1981)
Update date:2022-08-02
Topics: Palladium-catalyzed cross-coupling Oxidative Addition Reductive Elimination Stereoselectivity Transmetalation Catalytic Cycle Stereospecific synthesis
Miyaura, Norio
Suginome, Hiroshi
Suzuki, Akira
The reactions of (Z)-1-alkenyldisiamylboranes with (Z)- or (E)-1-alkenyl bromides in the presence of a catalytic amount of tetrakis(triphenylphosphine)palladium and sodium ethoxide gave the corresponding conjugated (Z,Z)- or (Z,E)-alkadiene with high ster
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