A STEREOSPECIFIC SYNTHESIS OF CONJUGATED (E,Z)- AND (Z,Z)-ALKADIENES BY A PALLADIUM-CATALYZED CROSS-COUPLING REACTION OF 1-ALKENYLBORANES WITH 1-ALKENYL BROMIDES

DOI: 10.1016/0040-4039(81)80166-9

Source and publish data:

Tetrahedron Letters p. 127 - 130 (1981)

Update date:2022-08-02

Topics: Palladium-catalyzed cross-coupling Oxidative Addition Reductive Elimination Stereoselectivity Transmetalation Catalytic Cycle Stereospecific synthesis

Authors:

Miyaura, Norio

Suginome, Hiroshi

Suzuki, Akira

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(81)80166-9

The reactions of (Z)-1-alkenyldisiamylboranes with (Z)- or (E)-1-alkenyl bromides in the presence of a catalytic amount of tetrakis(triphenylphosphine)palladium and sodium ethoxide gave the corresponding conjugated (Z,Z)- or (Z,E)-alkadiene with high ster

Full text of DOI:10.1016/0040-4039(81)80166-9

Products guided by the article

Product name:Benzene, [4-(1-cyclohexen-1-yl)-1,3-butadienyl]-, (Z,E)-

Cas No:77855-70-0

R&D Labs maybe for 77855-70-0

Shandong Xingshun New Material Co., Ltd.

website:http://www.sd-xingshun.com

Contact:+86-519-86461196

Address:Middle of Luhua East Road, Dingtao District
YanCheng LongShen Chemical Co.,Ltd.

Contact:+86-515-86668866

Address:No.13,Weiyi Road,Funing Aoyang Industrial Park
JIANGSU GRAND XINYI PHARMACEUTICAL CO.,LTD

website:http://www.xypharm.com/

Contact:+86-515-84383317

Address:Chenli Road,Costal Chemical Area Binhai,Yancheng, Jiangsu,China
Hangzhou Showland Technology Co., Ltd.

Contact:86-571-88920516

Address:ROOM2118,NO.553,WENSAN ROAD,HANGZHOU,CHINA
HOST COUNTRY LIMITED

Contact:+852 83038667

Address:Room 1502, 15th Floor, SPA Centre,53-55 Lockhart Road, Wanchai, Hong Kong

Relevant to this article

Covalent palladium-zinc bonds and their reactivity

Doi:10.1039/b709364k
(2007)
Total synthesis of FR901483

Doi:10.1021/ol015526i
(2001)
Direct C-H Cyanation of Arenes via Organic Photoredox Catalysis

Doi:10.1021/jacs.6b12708
(2017)
Tungsten(0) alkylidene complexes stabilized as pyridinium ylides: New aspects of their synthesis and reactivity

Doi:10.1016/S0022-328X(00)00727-0
(2001)
Doi:10.1016/S0040-4039(01)96869-8
(1971)
Carbon dioxide capture and use: Organic synthesis using carbon dioxide from exhaust gas

Doi:10.1002/anie.201308341
(2014)

Article Doi