THE REACTIONS OF PHENOLIC REAGENTS WITH α-BROMO MICHAEL ACCEPTORS IN THE K2CO3-ACETONE SYSTEM. A STEREOSPECIFIC AdSNE PROCESS.

DOI: 10.1016/0040-4039(81)80178-5

Source and publish data:

Tetrahedron Letters p. 167 - 168 (1981)

Update date:2022-09-26

Topics:

Authors:

Rosnati, Vittorio

Saba, Antonio

Salimbeni, Aldo

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(81)80178-5

α-bromo Michael acceptors undergo ipso-substitution by phenol or benzenethiol in the K2CO3-acetone system, the reaction originating the (Z) isomers, via a stereospecific Ad_SNE process.

Full text of DOI:10.1016/0040-4039(81)80178-5

Products guided by the article

Product name:(Z)-3-phenoxy-3-penten-2-one

Cas No:77873-92-8

R&D Labs maybe for 77873-92-8

Suzhou Ryan Pharmachem Technology Co.,Ltd

Contact:+86-0512-68780025

Address:B-301,No.2 Taishan Road,Suzhou New District,Jiangsu,P.R. China
He Bei Shun Er Chemical Co., LTD.

Contact:86-0311-86996932/86860168

Address:No 18,North street
NEW FORTUNE INDUSTRIAL CO.,LTD.

website:http://newfortune.lookchem.com/

Contact:+86-25-8645-9456

Address:C4-105 GREEN ISLAND FLOWER TOWN
Haitong Chemical Industrial Co.,Ltd.

website:https://www.haitonglongwin.com/

Contact:+86-022-66221018

Address:18-701, No.99, The 4th Street, TEDA,
Hebei Tianxiang Biological & Pharmaceutical Co., Ltd

Contact:86-0312-6615158

Address:No 42 fazhan street qingyuan county

Relevant to this article

Substitution and Elimination Reactions in Chloro Olefins. 3. Reactions of Methyl β-Chlorocinnamates with Thiophenoxide Ion

Doi:10.1021/jo00332a010
(1981)
Lead Promoted Barbier-Type Reaction of Propargyl Bromide with Aldehydes

Doi:10.1246/cl.1986.1461
(1986)
Organocatalytic phosphorylation of alcohols using pyridine- N -oxide

Doi:10.1055/s-0034-1379993
(2015)
Syntheses of Seleno Estrogens

Doi:10.1021/jo00330a005
(1981)
BIOSYNTHESIS OF TYLOPHORINE AND TYLOPHORININE

Doi:10.1016/S0040-4020(01)92028-9
(1981)
Allylic Chlorination of Gibberellins A₃ and A₇ Methyl Esters and of Gibberellin A₃: Preparation of Gibberellin A₅

Doi:10.1039/P19810000672
(1981)

Article Doi