Tetrahedron Letters p. 4887 - 4890 (1980)
Update date:2022-08-05
Topics:
Mayer, Bernd
Neumann, Wilhelm P.
Thermolysis of 22 7-silanorbornadienes (18 of them are new) forming silylene R2Si and the corresponding benzene derivatives is shown to be a two step reaction enhanced by higher stability of the intermediate biradical.Evidence for the latter is given by trapping and ESR experiments.
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