Chiral Acyl Anion Equivalents: Asymmetric Synthesis of 11-Deoxy-ent-Prostaglandin Intermediates

DOI: 10.1039/P19810001284

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 1284 - 1286 (1981)

Update date:2022-08-03

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Authors:

Colombo, Lino

Gennari, Cesare

Resnati, Giuseppe

Scolastico, Carlo

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Article abstract of DOI:10.1039/P19810001284

Conjugate addition of the chiral formyl anion equivalent p-tolyl p-tolylthiomethyl sulphoxide (+)-(S)-(1) to the cyclopentenone derivative (2a) leads to the adduct (3a) in 45percent yield with high diastereoselectivity.Reduction of (3a) gives the dithioac

Full text of DOI:10.1039/P19810001284

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