Journal of Organometallic Chemistry p. 317 - 326 (1981)
Update date:2022-08-05
Topics:
Adeleke, Babatunde B.
Chen, Kuang S.
Wan, Jeffrey K.S.
Various reactions of Group IVB organometallic radicals with 4,4'-dimethoxybenzophenone, 4,4'-dimethoxythiobenzophenone, and 3-ethyl-2-thioxo-4-oxazolidione were studied by ESR spectroscopy.The greater involvement of sulfur in comparison with oxygen in spin delocalization is clearly reflected in both the hyperfine coupling constants and the g-factors.In general, thiocarbonyl compounds appear to be more efficient in forming radical adducts than the corresponding carbonyl compounds but the overall reactions depend strongly upon the structure of the thiocarbonyl compounds.
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Doi:10.1002/ardp.19813140209
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