Intramolecular Photocycloadditions-Cyclobutane Fragmentation: Total Synthesis of (+/-)-Pentalenene, (+/-)-Pentalenic Acid, and (+/-)-Deoxypentalenic Acid

DOI: 10.1021/ja00264a037

Source and publish data:

Journal of the American Chemical Society p. 800 - 806 (1986)

Update date:2022-08-03

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Authors:

Crimmins, Michael T.

DeLoach, Joe A.

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Article abstract of DOI:10.1021/ja00264a037

Pentalenene, pentalenic acid, and deoxypentalenic acid, important metabolites in the biosynthesis of the pentalenolactones, have been synthesized from methyl isobutyrate through a common intermediate.The initial key stp involves a novel conjugate addition

Full text of DOI:10.1021/ja00264a037

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