A NEW SYNTHESIS OF 2,3,4,6-TETRA-O-BENZYL-D-GLUCOPYRANOSYLIDENE ACETALS, USING TRIMETHYLSILYL TRIFLUOROMETHANESULFONATE AS THE CATALYST

DOI: 10.1016/0008-6215(83)84015-4

Source and publish data:

Carbohydrate Research p. 175 - 186 (1983)

Update date:2022-08-04

Topics: Synthesis Lewis acid Catalyst Protecting group Glycosylation Workup Reaction Monitoring Acetals Anomeric position

Authors:

Horito, Shigeomi

Asano, Katsuji

Umemura, Kazuyuki

Hashimoto, Hironobu

Yoshimura, Juji

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Article abstract of DOI:10.1016/0008-6215(83)84015-4

The title compounds were synthesized by condensation of 2,3,4,6-tetra-O-benzyl-D-glucono-1,5-lactone with bis-O-(trimethylsilyl)-1,2-diols in the presence of trimethylsilyl trifluoromethanesulfonate as the catalyst.Application to cis- and trans-1,2-diols

Full text of DOI:10.1016/0008-6215(83)84015-4

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