Tetrahedron Letters p. 1115 - 1118 (1981)
Update date:2022-09-26
Topics:
Ochiai, Masahito,
Arimoto, Masao
Fujita, Eiichi
Michael addition of allylsilane to α-nitro olefin in the presence of AlCl3 proceeded smoothly at low temperature to give unsaturated nitronic acid, which was converted into the γδ-enone using aqueous Ti (III).Transformation of the enone into the 1,4-diketone followed by the intramolecular aldol condensation with the latter provided a convenient new synthesis of cyclopentanone.
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Doi:10.1021/jo00333a046
(1981)Doi:10.1007/BF00953465
(1983)Doi:10.1021/jp993245a
(2000)Doi:10.1016/S0040-4020(01)97969-4
(1981)Doi:10.1002/anie.202007030
(2020)Doi:10.1021/jo00335a072
(1981)
