Intermolecular Cobalt-mediated Cycloadditions: Regiospecific One-step Construction of Bicyclic Dienes from α,ω-Enynes and Alkynes

DOI: 10.1039/c39810000053

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Journal of the Chemical Society. Chemical communications p. 53 - 55 (1981)

Update date:2022-09-26

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Authors:

Chang, Chu-An

King, Joseph A.

Vollhardt, K. Peter C.

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Article abstract of DOI:10.1039/c39810000053

α,ω-Enynes are co-cyclised with alkynes and stoicheiometric amounts of dicarbonyl(cyclopentadienyl)cobalt to furnish bicyclic-diene cobalt complexes and their free ligands regiospecifically, the former being convertible into the latter by oxidative demeta

Full text of DOI:10.1039/c39810000053

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