2-(TRIMETHYLSILYL)ETHYL CHLOROFORMATE: A CONVENIENT REAGENT FOR PROTECTION OF HYDROXYL FUNCTION

DOI: 10.1016/0040-4039(81)89023-5

Source and publish data:

Tetrahedron Letters p. 969 - 972 (1981)

Update date:2022-08-02

Topics:

Authors:

Gioeli, Carlo

Balgobin, Neil

Josephson, Staffan

Chattopahyaya, Jyoti B.

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Article abstract of DOI:10.1016/0040-4039(81)89023-5

2-(Trimethylsilyl)ethyl chloroformate reacts with alcohols to give carbonates in high yield. n-Bu4NF in THF(0.2M) solution for 10 min or ZnBr2 or ZnCl2 in CH3NO2 for 10 min regenerate the alcohol at 20 deg C.

Full text of DOI:10.1016/0040-4039(81)89023-5

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