SYNTHETIC APPROACH TO GRAYANOTOXINS AND ASEBOTOXINS: A NEW CONSTRUCTION OF THE A-HOMOGRAYANOTOXANE RING SYSTEM

DOI: 10.1016/S0040-4020(01)98878-7

Source and publish data:

Tetrahedron p. 3813 - 3818 (1981)

Update date:2022-08-03

Topics:

Authors:

Kametani, Tetsuji

Matsumoto, Hiroo

Honda, Toshio

Fukumoto, Keiichiro

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Article abstract of DOI:10.1016/S0040-4020(01)98878-7

The tetracyclic compounds (3 and 4) corresponding to A-homograyanotoxane system were synthesised by a thermolysis of the benzocyclobutene (8), followed by a Wagner-Meerwein rearrangement of the kaurane type of compounds (15 and 16).

Full text of DOI:10.1016/S0040-4020(01)98878-7

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