STEREOSELECTIVE SYN EPOXIDATION OF THE DIHYDRODIOLS OF DIBENZANTHRACENE AND 7-METHYLBENZANTHRACENE

DOI: 10.1016/S0040-4039(01)90403-4

Source and publish data:

Tetrahedron Letters p. 1657 - 1660 (1981)

Update date:2022-08-05

Topics:

Authors:

Lee, Hongmee

Harvey, Ronald G.

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Article abstract of DOI:10.1016/S0040-4039(01)90403-4

Epoxidation of the bay region dihydrodiols of the title hydrocarbons affords stereoselectively the corresponding syn diol epoxides rather than the anticipated isomeric anti diol epoxides, indicative of a dominant cis-directing effect of the benzylic vs the allylic hydroxyl groups.

Full text of DOI:10.1016/S0040-4039(01)90403-4

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