Pyrimidine Derivatives and Related Compounds. Part 36. Nucleophilic Addition Reaction of a Cyanide Ion to 6-Substituted 1,3-Dimethyl-5-nitrouracils. Synthesis of 5,6-Dihydrouracil and 5,6-Dihydrocyclothymine Derivatives

DOI: 10.1039/P19810001896

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 1896 - 1899 (1981)

Update date:2022-08-02

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Authors:

Hirota, Kosaku

Yamada, Yoshihiro

Asao, Tetsuji

Senda, Shigeo

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Article abstract of DOI:10.1039/P19810001896

6-Substituted 1,3-dimethyl-5-nitrouracils (3a-c) react with potassium cyanide to dive stereospecifically the 6-cyano-5-nitro-5,6-dihydrouracils (4a-c).Reaction of 6-bromomethyl-1,3-dimethyl-5-nitrouracil (7) with potassiun cyanide gives 6-cyano-1,3-dimeth

Full text of DOI:10.1039/P19810001896

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