Unexpected 1,3-oxazolidine formation in the attempted oxidation of N- aryl-N-methyl substituted β-amino alcohols using pyridinium dichromate

DOI: 10.1016/S0040-4039(98)00289-5

Source and publish data:

Tetrahedron Letters p. 2269 - 2272 (1998)

Update date:2022-08-05

Topics:

Authors:

Yli-Kauhaluoma, Jari T.

Harwig, Curtis W.

Wentworth Jr., Paul

Janda, Kim D.

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Article abstract of DOI:10.1016/S0040-4039(98)00289-5

1,3-Oxazolidines were obtained from the reaction of N-methyl substituted β-amino alcohols with pyridinium dichromate in dichloromethane. A single electron transfer mechanism, SET, is proposed to account for the formation of the 1,3-oxazolidines.

Full text of DOI:10.1016/S0040-4039(98)00289-5

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