The First Bis Gem Donor-Acceptor Substituted Allene: Synthesis, Geometry, and Electronic Structure

DOI: 10.1021/ja00410a027

Source and publish data:

Journal of the American Chemical Society p. 6142 - 6147 (1981)

Update date:2022-08-04

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Authors:

Weiss, Robert

Wolf, Hilmar

Schubert, Ulrich

Clark, Timothy

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Article abstract of DOI:10.1021/ja00410a027

The synthesis of 1,3-bis(dimethylamino)-1,3-bis(triphenylphosphino)allene diiodide (12), the first bis gem donor-acceptor substituted allene, is reported.The X-ray structure of this salt shows geometrical features such as a twist toward a trans planar geo

Full text of DOI:10.1021/ja00410a027

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