IRIDOIDS : NOVEL TOTAL SYNTHESIS OF (+/-)-ISOIRIDOMYRMECIN AND OF (+/-)-VERBENALOL

DOI: 10.1016/S0040-4020(01)97962-1

Source and publish data:

Tetrahedron p. 2085 - 2090 (1981)

Update date:2022-09-26

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Authors:

Callant, Paul

Ongena, Raymond

Vandewalle, Maurits

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Article abstract of DOI:10.1016/S0040-4020(01)97962-1

A novel synthesis of the iridoids (+/-)-isoiridomyrmecin 1 and (+/-)-verbenalol 2 is described starting from the tricyclo<3.3.0.0^2,8>octan-3-one 3, using cis fused bicyclo<3.3.0>octenes as intermediates.The heterocyclic ring of iridoids was formed in the final stages of the synthesis.

Full text of DOI:10.1016/S0040-4020(01)97962-1

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