Structural Modifications of Chaparrinone Using Benzeneseleninic Anhydride

DOI: 10.1002/hlca.19810640530

Source and publish data:

Helvetica Chimica Acta p. 1540 - 1544 (1981)

Update date:2022-09-26

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Authors:

Khoi, Nguyen

Polonsky, Judith

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Article abstract of DOI:10.1002/hlca.19810640530

Treatment of chaparrinone triacetate with benzeneseleninic anhydride afforded in addition to the Δ^14,15-dehydro compound two products arising from angular hydroxylation at C(5).The mechanism of this reaction is discussed.The corresponding deacetylated compounds do not display significant antineoplastic activity.

Full text of DOI:10.1002/hlca.19810640530

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