New Synthesis of 2-Substituted 2-Oxazolines: Transition-Metal-Catalyzed Cross-Coupling of Grignards with 2-(Methylthio)-4,4-dimethyl-2-oxazoline

DOI: 10.1021/jo00339a032

Source and publish data:

Journal of Organic Chemistry p. 5402 - 5404 (1981)

Update date:2022-08-04

Topics:

Authors:

Pridgen, Lendon N.

Killmer, Lewis B.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00339a032

A new synthesis of 2-aryl-4,4-dimethyl-2-oxazolines (18a-e) using nickel- and palladium-phosphine complexes to catalyze cross-coupling of Grignard reagents 17 with 2-(methylthio)-4,4-dimethyl-2-oxazoline (16) is described.This reaction represents the firs

Full text of DOI:10.1021/jo00339a032

Products guided by the article

Product name:2-(3,4-dimethylphenyl)-4,4-dimethyl-2-oxazoline

Cas No:79568-31-3

R&D Labs maybe for 79568-31-3

Zhejiang Sucon Silicone Co.,Ltd

Contact:+86-575-88046692

Address:Qisheng Rd., Paojiang Industrial Zone, Shaoxing, Zhejiang, China.
LianYunGang Chiral Chemical(CHINA) CO.,LTD

Contact:+86-518-83616958 +86-519-82884848

Address:LianYunGang Chemical Industry Park (JiangSu)
Qingzhou Baibang import and export co.,Ltd

Contact:+86-536-3265899

Address:No.338, Tuoshan Road
Beijing Wisdom Chemicals Co., Ltd.

Contact:+86-10-52350335

Address:F2, BLDG 19, Liando Valley U, Majuqiao, Tongzhou District, Beijing, China
Ningjiang Chemical Factory

website:http://pharmchemlabs.lookchem.com/

Contact:+86-576-88283887

Address:Yantou Chemical Industry Zone,Jiaojiang

Relevant to this article

STERIC ASPECTS OF THE OXIDATION OF THIOKETONES BY SINGLET OXYGEN

Doi:10.1246/cl.1982.89
(1982)
2-Azacephems

Doi:10.1016/S0040-4020(01)90532-0
(1990)
The Smiles Rearrangement of 2-Aryloxy-5-nitrophenoxides. Attempted Routes to Benzoxirens and Tribenzotrioxonins

Doi:10.1039/P19810002456
(1981)
Combined 2H and 18O Isotop Effects in Support of a Concerted, Synchronous Elimination of Acetaldehyde from a Bis(benzyl ethyl ether) Radical Cation

Doi:10.1021/ja00227a002
(1988)
Influence of the alkyl spacer length on the phase transition behaviour of the Λ-shaped liquid crystal

Doi:10.1080/15421400590956225
(2005)
INTRAMOLECULAR CONDENSATION OF N-HOMOPIPERONYL-N-DIALKYLPHOSPHORYL GLYCINE UNDER THE CATALYSIS OF LEWIS ACID

Doi:10.1016/S0040-4039(00)81725-6
(1983)

Article Doi