Journal of Organic Chemistry p. 4482 - 4485 (1982)
Update date:2022-07-31
Topics:
Calo, Vincenzo
Lopez, Luigi
Pesce, Giannangelo
Calianno, Antonia
An efficient control of the regio- and stereochemistry in the allylic substitutions with organomagnesium compounds has been achieved by using 2-(allyloxy)benzothiazoles as substrates in the presence of copper bromide.The selectivity is due to the coordinative effects of the substrates toward the organometallic species.
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