Selectivity in the Allylic Substitutions with Organometallics through Neighboring Coordination. 2-(Allyloxy)benzothiazoles as SN2' Electrophiles for Regio- and Stereoselective Olefin Syntheses

DOI: 10.1021/jo00144a016

Source and publish data:

Journal of Organic Chemistry p. 4482 - 4485 (1982)

Update date:2022-07-31

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Authors:

Calo, Vincenzo

Lopez, Luigi

Pesce, Giannangelo

Calianno, Antonia

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Article abstract of DOI:10.1021/jo00144a016

An efficient control of the regio- and stereochemistry in the allylic substitutions with organomagnesium compounds has been achieved by using 2-(allyloxy)benzothiazoles as substrates in the presence of copper bromide.The selectivity is due to the coordinative effects of the substrates toward the organometallic species.

Full text of DOI:10.1021/jo00144a016

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