
Chemistry Letters p. 729 - 732 (1983)
Update date:2022-08-04
Topics:
Saito, Akira
Matsushita, Hajime
Kaneko, Hajime
Cyclization of trans-β-monocyclohomofarnesic acid and the related compounds was closely examined in order to elucidate the reaction mechanism.It was revealed that the cyclization of trans-β-monocyclohomofarnesic acid proceeds via formation of the cationic intermediate followed by concerted lactonization to give trans-anti-trans norambreinolide stereoselectively.
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