Journal of the Chemical Society. Perkin transactions I p. 2411 - 2414 (1981)
Update date:2022-08-02
Topics:
Sato, Kikumasa
Inoue, Seiichi
Watanabe, Kiyoshi
A new ?-allylnickel(II) complex, di-μ-bromo-bis(1-3-η-2-methyl-6-methyleneocta-2,7-dienyl)dinickel (5) was prepared by the reaction of bromomyrcene (7a) and (8a) with nickel tetracarbonyl in benzene.The reaction of the complex (5) with iodobenzene in dimethylformamide afforded 8-phenylmyrcene (10) in a high degree of stereoselectivity (E/Z = 85/15).The complex (5) reacted with the chloro-acetal (14), derived in three steps from isoprene, to give the acetal (15) which upon hydrolysis afforded β-sinensal (1) in high stereoselectivity (93percentE).
View MoreShaanxi HuaTai Bio-fine chemical company Ltd
Contact:86-029-87862197
Address:No. 5, 3rd Floor, 29 Yanta North Road, Beilin Dist.
Contact:852-29282288
Address:HONGKONG
KINHENG CHEMICAL(SHANGHAI)CO., LTD.
Contact:+8621-60490170
Address:Room401, No.28,Lane 189, Yangshupu Rd. Shanghai, China.
Contact:021-36356756
Address:Room601,Building No.14,280 Yangcheng Road,Shanghai
Zipont chem(wuhan)Tech co.,Ltd
Contact:+86-27-87587198
Address:wuhan
Doi:10.1016/j.jorganchem.2008.12.039
(2009)Doi:10.1055/s-0028-1087918
(2009)Doi:10.1002/chem.200801892
(2009)Doi:10.1039/C39880000506
(1988)Doi:10.1021/acs.orglett.0c02071
(2020)Doi:10.1002/ejic.200800094
(2008)