Journal of the Chemical Society. Perkin transactions I p. 2411 - 2414 (1981)
Update date:2022-08-02
Topics:
Sato, Kikumasa
Inoue, Seiichi
Watanabe, Kiyoshi
A new ?-allylnickel(II) complex, di-μ-bromo-bis(1-3-η-2-methyl-6-methyleneocta-2,7-dienyl)dinickel (5) was prepared by the reaction of bromomyrcene (7a) and (8a) with nickel tetracarbonyl in benzene.The reaction of the complex (5) with iodobenzene in dimethylformamide afforded 8-phenylmyrcene (10) in a high degree of stereoselectivity (E/Z = 85/15).The complex (5) reacted with the chloro-acetal (14), derived in three steps from isoprene, to give the acetal (15) which upon hydrolysis afforded β-sinensal (1) in high stereoselectivity (93percentE).
View MoreTaizhou Huading Chemical Co.,Ltd(expird)
Contact:+86-576-88583898
Address:Economic&Technology development zone,Taizhou City,Zhejiang Province,China
Anhui Xinyuan Technology Co.,Ltd
Contact:0086-559-3515800
Address:No.16 Zijin Rd, Circular Economic Zone, Huizhou District, Huangshan Anhui China
Tianjin Chemsyntech Chemical Co., Ltd
Contact:+86-22-60872258
Address:Haitai green industry base in Tianjin, K1,5-601
website:http://www.eastarchem.com/
Contact:1-800-898-2436
Address:1215 K Street, STE 1700
SHUNYUANSHENG BIO-PHARMTECH CO., LTD
website:https://www.whsysbio.com
Contact:--
Address:Building 13, Liandong U Valley-Wuhan Economic Innovation Valley, No. 259, Xingsan Road, Shamao Street, Hannan District, Wuhan City, Hubei Province
Doi:10.1016/j.jorganchem.2008.12.039
(2009)Doi:10.1055/s-0028-1087918
(2009)Doi:10.1002/chem.200801892
(2009)Doi:10.1039/C39880000506
(1988)Doi:10.1021/acs.orglett.0c02071
(2020)Doi:10.1002/ejic.200800094
(2008)
