Journal of the Chemical Society. Perkin transactions I p. 2411 - 2414 (1981)
Update date:2022-08-02
Topics:
Sato, Kikumasa
Inoue, Seiichi
Watanabe, Kiyoshi
A new ?-allylnickel(II) complex, di-μ-bromo-bis(1-3-η-2-methyl-6-methyleneocta-2,7-dienyl)dinickel (5) was prepared by the reaction of bromomyrcene (7a) and (8a) with nickel tetracarbonyl in benzene.The reaction of the complex (5) with iodobenzene in dimethylformamide afforded 8-phenylmyrcene (10) in a high degree of stereoselectivity (E/Z = 85/15).The complex (5) reacted with the chloro-acetal (14), derived in three steps from isoprene, to give the acetal (15) which upon hydrolysis afforded β-sinensal (1) in high stereoselectivity (93percentE).
View MoreWeifang Jahwa Chemical Co.,Ltd
Contact:0086-536-8897731,8897730
Address:No.5166 East Dongfeng Street,Weifang,Shandong,China
Qingdao little fox Biological &Technology Co.,Ltd
Contact:86--15064871218
Address:Cangshun Road, Licang District, Qingdao Building 26, Unit 1, Unit 4,Room 301
Shanghai Petrochemical Co.,Ltd
Contact:15252503096
Address:Room 102,Purple Crystal Court, Lane 398,#35,Sunnong Road,Pudong New Area,
Shanghai Xinda Pharmaceuticals Co., Ltd.
Contact:86-21-33692333-8008
Address:999 Linxian Road, Jinshan Industrial Park, Shanghai, China
Changzhou Jiana Chemical Co.,Ltd
website:http://www.jianachem.com
Contact:86-0519-88731808
Address:Zhenglu Town Wujin City, Jiangsu Province
Doi:10.1016/j.jorganchem.2008.12.039
(2009)Doi:10.1055/s-0028-1087918
(2009)Doi:10.1002/chem.200801892
(2009)Doi:10.1039/C39880000506
(1988)Doi:10.1021/acs.orglett.0c02071
(2020)Doi:10.1002/ejic.200800094
(2008)
