3-alkenyl-2-silyloxyindoles: An enabling, yet understated progeny of vinylogous carbon nucleophiles

DOI: 10.1002/ejoc.201101446

Source and publish data:

European Journal of Organic Chemistry p. 466 - 470 (2012)

Update date:2022-07-30

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Authors:

Rassu, Gloria

Zambrano, Vincenzo

Tanca, Rossella

Sartori, Andrea

Battistini, Lucia

Zanardi, Franca

Curti, Claudio

Casiraghi, Giovanni

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Article abstract of DOI:10.1002/ejoc.201101446

We introduce novel 3-alkenyl-2-silyloxyindole nucleophiles and demonstrate their utility by developing an unprecedented vinylogous Mukaiyama-type aldol reaction with aromatic aldehydes. This reaction displays excellent levels of γ-site selectivity and dia

Full text of DOI:10.1002/ejoc.201101446

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