THE ACTIVITY SCALE OF DIPOLAROPHILES VERSUS THIOBENZOPHENONE S-METHYLIDE

DOI: 10.1016/S0040-4039(00)88294-5

Source and publish data:

Tetrahedron Letters p. 4185 - 4188 (1983)

Update date:2022-08-03

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Authors:

Huisgen, Rolf

Xingya, Li

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Article abstract of DOI:10.1016/S0040-4039(00)88294-5

Competition experiments of pairs of dipolarophiles for thiobenzophenone (2) furnish relative rate constants which reveal an unusually high selectivity of the nucleophilic 1,3-dipole, in accordance with Sustmann's PMO concept.

Full text of DOI:10.1016/S0040-4039(00)88294-5

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