Journal of the Chemical Society. Chemical communications p. 1461 - 1464 (1984)
Update date:2022-08-03
Topics:
Allwood, Billy L.
Shahriari-Zavareh, Hooshang
Stoddart, J. Fraser
Williams, David J.
Enantioselective reductions of prochiral aromatic ketones with adducts formed between ammonia-borane and (2R,3R,11R,12R)- and (2S,3S,11S,12S)-tetraphenyl-1,4,7,10,13,16-hexaoxacyclo-octadecane, (RRRR)-(3) and (SSSS)-(3), have afforded the corresponding (S) and (R) aromatic secondary alcohols with enantiomeric excesses of 20-67percent.
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