Bulletin of the Chemical Society of Japan p. 3084 - 3087 (1981)
Update date:2022-08-05
Topics:
Ishikawa, Nobuo
Butler, Sigmund
Maruta, Masamichi
Nucleophilic reactions of F-2-methyl-2-pentene (1) and (E)-F-4-methyl-2-pentene (2), the dimers of hexafluoropropene, with organomagnesium and -lithium reagents were investigated.The reaction of 1 proceeded readily, giving two alkyl- or aryl-substituted polyfluoroalkenes with resulted from α- and γ-fluorine elimination, respectively.Only phenyllithium reacted with 2, giving also α- and γ-fluorine eliminated phenylpolyfluoroalkenes.The reaction mechanism of γ-elimination was postulated in relation to the electropositive property of the organo group and to Mg-F or Li-F bond formation.
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Doi:10.1007/BF00963426
(1981)Doi:10.1021/ic950846h
(1996)Doi:10.1002/ejic.202100022
(2021)Doi:10.1007/BF00846405
()Doi:10.1134/S0036023618050200
()Doi:10.1246/bcsj.54.2790
(1981)