NITROALLYLATION OF HIGHLY REACTIVE ORGANOLITHIUM COMPOUNDS BY 2-NITRO-3-PIVALOYLOXI-1-PROPENE (NPP)

DOI: 10.1016/S0040-4039(01)81868-2

Source and publish data:

Tetrahedron Letters p. 3223 - 3226 (1981)

Update date:2022-08-05

Topics:

Authors:

Knochel, Paul

Seebach, Dieter

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Article abstract of DOI:10.1016/S0040-4039(01)81868-2

The nitroolefin 1 (NPP) efficiently transfers a 2-nitroallyl group even to the most reactive nucleophilic centres of organolithium reagents to give the products of type 2 listed in the table.

Full text of DOI:10.1016/S0040-4039(01)81868-2

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