Photochemistry of 9-phenanthrenes. Intramolecular Addition of Amines to Excited State of Phenanthrene in Conformationally Rigid System

DOI: 10.1246/bcsj.54.3500

Source and publish data:

Bulletin of the Chemical Society of Japan p. 3500 - 3504 (1981)

Update date:2022-08-05

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Authors:

Sugimoto, Akira

Sumida, Ryozo

Tamai, Naoto

Inoue, Hiroo

Otsuji, Yoshio

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Article abstract of DOI:10.1246/bcsj.54.3500

Irradiation of benzene solutions of 9-<2-(N-substituted aminomethyl)-1-naphthyl>phenanthrenes (3a-d) gave pyrroline derivatives by the attack of NH group on the C-9 carbon atom of the phenanthrene ring.The reactions were highly selective in regio- and ste

Full text of DOI:10.1246/bcsj.54.3500

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