GOLD(I) AND PLATINUM(II) AZOLATES AS LIGANDS IN CATIONIC RHODIUM(I) COMPLEXES

DOI: 10.1016/S0022-328X(00)89059-2

Source and publish data:

Journal of Organometallic Chemistry p. 249 - 256 (1981)

Update date:2022-09-26

Topics:

Authors:

Uson, R.

Oro, L. A.

Ciriano, M. A.

Pinillos, M. T.

Cabeza, J. A.

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Article abstract of DOI:10.1016/S0022-328X(00)89059-2

Several cationic heterometallic rhodium complexes have been obtained by using the complexes ImAuPPh3 or (az)2Pt(dpe) (az=imidazolate (Im) or pyrazolate (Pz) anions) as ligands.Attempts to prepare rhodium(I)-gold(I) derivatives containing pyrazolate-bridging ligands proved unsuccessful, rearrangements giving the complexes 2 and ClO4, ClO4 or AuClPPh3 as end-products.

Full text of DOI:10.1016/S0022-328X(00)89059-2

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Product name:[(COD)Ir(μ-Pz)2Pt(dpe)]ClO4 COD=cyclooctadiene Pz=pyrazolate dpe=1,2-bis(diphenylphosphino)ethane

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